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Abstract A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet’s initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultrahot Jupiter WASP-121 b using the high-resolution (R= 45,000) IGRINS instrument on Gemini South. Probing the planet’s direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly superstellar C/O ratio of ${0.70}_{-0.10}^{+0.07}$and a moderately superstellar refractory-to-volatile ratio at ${3.83}_{-1.67}^{+3.62}\times$stellar. This combination is most consistent with formation between the soot line and H₂O snow line, but we cannot rule out formation between the H₂O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H₂O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet dayside. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high-resolution spectroscopy in the near-IRHandKbands. 

Abstract Ground-based high-resolution and space-based low-resolution spectroscopy are the two main avenues through which transiting exoplanet atmospheres are studied. Both methods provide unique strengths and shortcomings, and combining the two can be a powerful probe into an exoplanet’s atmosphere. Within a joint atmospheric retrieval framework, we combined JWST NIRSpec/G395H secondary eclipse spectra and Gemini South/IGRINS pre- and post-eclipse thermal emission observations of the hot Jupiter WASP-77A b. Our inferences from the IGRINS and NIRSpec data sets are consistent with each other, and combining the two allows us to measure the gas abundances of H₂O and CO, as well as the vertical thermal structure, with higher precision than either data set provided individually. We confirm WASP-77A b’s subsolar metallicity ([(C+O)/H] = −0.61 ${}_{-0.09}^{+0.10})$and solar C/O ratio (C/O = 0.57 ${}_{-0.06}^{+0.06})$. The two types of data are complementary, and our abundance inferences are mostly driven by the IGRINS data, while inference of the thermal structure is driven by the NIRSpec data. Our ability to draw inferences from the post-eclipse IGRINS data is highly sensitive to the number of singular values removed in the detrending process, potentially due to high and variable humidity. We also search for signatures for atmospheric dynamics in the IGRINS data and find that propagated ephemeris error can manifest as either an orbital eccentricity or a strong equatorial jet. Neither are detected when using more up-to-date ephemerides. However, we find moderate evidence of thermal inhomogeneity and measure a cooler nightside that presents itself in the later phases after secondary eclipse. 

Abstract Close-in lava planets represent an extreme example of terrestrial worlds, but their high temperatures may allow us to probe a diversity of crustal compositions. The brightest and most well-studied of these objects is 55 Cancri e, a nearby super-Earth with a remarkably short 17 hr orbit. However, despite numerous studies, debate remains about the existence and composition of its atmosphere. We present upper limits on the atmospheric pressure of 55 Cnc e derived from high-resolution time-series spectra taken with Gemini-N/MAROON-X. Our results are consistent with current crustal evaporation models for this planet which predict a thin ∼100 mbar atmosphere. We conclude that, if a mineral atmosphere is present on 55 Cnc e, the atmospheric pressure is below 100 mbar. 

Abstract The spectroscopic characterization of terrestrial exoplanets over a wide spectral range from the near- to the mid-infrared will be made possible for the first time with the JWST. One challenge is that it is not known a priori whether such planets possess optically thick atmospheres or even any atmospheres altogether. However, this challenge also presents an opportunity, the potential to detect the surface of an extrasolar world. This study explores the feasibility of characterizing with the JWST the atmosphere and surface of LHS 3844b, the highest signal-to-noise rocky thermal emission target among planets that are cool enough to have nonmolten surfaces. We model the planetary emission, including the spectral signal of both the atmosphere and surface, and we explore all scenarios that are consistent with the existing Spitzer 4.5 μ m measurement of LHS 3844b from Kreidberg et al. In summary, we find a range of plausible surfaces and atmospheres that are within 3 σ of the observationless reflective metal-rich, iron-oxidized, and basaltic compositions are allowed, and atmospheres are restricted to a maximum thickness of 1 bar, if near-infrared absorbers at ≳100 ppm are included. We further make predictions on the observability of surfaces and atmospheres and find that a small number (∼3) of eclipse observations should suffice to differentiate between surface and atmospheric features. We also perform a Bayesian retrieval analysis on simulated JWST data and find that the surface signal may make it harder to precisely constrain the abundance of atmospheric species and may falsely induce a weak H 2 O detection. 

Abstract Close-in giant exoplanets with temperatures greater than 2,000 K (‘ultra-hot Jupiters’) have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble Space Telescope (HST) and Spitzer Space Telescope^1–3. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis^3–12. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS¹³instrument on the JWST. The data span 0.85 to 2.85 μm in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at >6σconfidence) and evidence for optical opacity, possibly attributable to H⁻, TiO and VO (combined significance of 3.8σ). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy-element abundance (‘metallicity’,$${\rm{M/H}}=1.0{3}_{-0.51}^{+1.11}$$ $\mathrm{M/H}=1.03_{-0.51}^{+1.11}$times solar) and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the substellar point that decreases steeply and symmetrically with longitude towards the terminators.